Laibach -> Triest via villa obcalina?

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Maribor 12:48 S2 17
Ljubljana 14:38

Ljubljana 17:45 IC 509
Divaca 19:17

Divaca 20:33 R 1762
Villa Opicina 20:55

The Slowenian Webpage say 35€ - 40€. Is that true?
And is there an Railplus Discount because i travel internationally Sezana -> Villa Opicina?

Maribor 12:48 S2 17
Ljubljana 14:38

Ljubljana 17:45 IC 509
Divaca 19:17

Divaca 20:33 R 1762
Villa Opicina 20:55

The Slowenian Webpage say 35€ - 40€. Is that true?

Hmm? Which Slovenian webpage? It's way too much, since Maribor-Sežana (last Slovenian station before the border) is 22,39 euro with use of pendolino or 15,81 euro with regional trains, while Sežana-Villa Opicina is only 1 euro (or even free for some passengers, see http://www.slo-zeleznice.si/sl/potniki/tujina/italija/opcine )

And is there an Railplus Discount because i travel internationally Sezana -> Villa Opicina?

Yes, but it's way cheaper to "break" the ticket via Sežana. Absolutely no point to overpay for international ticket for the entire route

Maribor - Laibach ICS 24,21 €
Laibach - Divača IC 13,35 €
Divača - Sežana 1,28 €
+1€
39,84€

Absolutely no point to overpay for international ticket for the entire route

International Fare cost more?

Maribor - Laibach ICS 24,21 €
Laibach - Divača IC 13,35 €
Divača - Sežana 1,28 €
+1€
39,84€

Where are you getting these numbers? You should check Slovenian Railways (SZ) website (www.slo-zeleznice.si/en), Maribor to Ljubljana with ICS is 16+ euro, Maribor-Ljubljna-Sezana (22,39 with ICS on Maribor-Ljubljana leg), Maribor-Ljubljna-Sezana is 15,81 (if you don't use ICS trains)

International Fare cost more?

Standard full fare SCIC-NRT ticket Maribor-Villa Opicina should be 50+ euro

Where are you getting these numbers?

from the same Page.

Where are you getting these numbers?

from the same Page.

Ok, misunderstanding seems to be in the fact that you've searched for 1st class fare, while I was looking at 2nd class ))) So if you indeed want to travel with 1st class (and extra train change in Divaca), then fares you've quoted are right. With ICS 1st class Maribor-Ljubljana + Ljubljana-Sezana 2nd class it will cost you 33+ euro.
SCIC-NRT 1st class ticket Maribor-Villa Opicina is 75 euro, however no 1st class on Divaca-Sezana-Villa Opicina part

When you go to https://www.helloe.com and add the Voucher Code: "BUSGURU" you can save 10€ per Booking
Thats so nice! (Wien 9€ ->) Graz - Maribor = 0€
Triest - Laibach = 0€ -> Laibach -> Wien = 13€

Yep, bus is an option. However you probably shouldn't expect 1st class comfort from those lowcost bus companies

You can see my Pictures here: http://www.styria-mobile.at/home/forum/index.php?PHPSESSID=lv3v6on4lcu481l8p2n1uebkl7&topic=11211.msg150594#msg150594

Well, looks better than Polskibus, but not as good as OeBB InterCity buses. Anyhow, it's good to have a choice, both bus/train & fares

but not as good as OeBB InterCity buses.

The 1Class is quite ok.

Anyhow, it's good to have a choice, both bus/train & fares

Thats rite. But 9€ from Vienna to Maribor is impossible with the ÖBB.
And there is only one direct Train and many Bus.