Gorizia to Milan

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Do I need to book/buy tickets now to travel  on 22 June, and can I just buy them then on the stations there for the same price as now?

When traveling from Gorizia to Milan you will inevitably change trains at least one (in most cases change station will be Vencie-Mestre). On leg from Gorizia to Venice there is only regional trains without compulsory seat reservation and with the same ticket price no matter when you buy, thus there is absolutely no need to buy ticket in advance. But on leg from Venice to Milan, as was already said in the other topic, you can use either similar regional train (again no need to buy ticket in advance) or opt for high-speed Frecciabianca train, here you can get discounted tickets (start from 9 euro) if you buy in advance via TrenItalia website